GREEN DIESEL: BAHAN BAKAR CAIR TERBARUKAN PENGGANTI BIODIESEL
DOI:
https://doi.org/10.33795/distilat.v8i4.486Keywords:
biomassa, energi terbarukan, green diesel, teknologi produksiAbstract
Penggunaan bahan bakar yang berasal dari fosil hingga saat ini masih meningkat. Hal ini dikhawatirkan akan menyebabkan kelangkaan dan ketersediaannya di lapangan semakin menipis. untuk itu, perlu adanya sebuah inovasi yaitu produksi energi alternatif. Green diesel adalah solusi untuk mengatasi kebutuhan bakan bakar diesel yang terus meningkat. Green diesel juga sering disebut sebagai biofuel yang dianggap sebagai diesel terbarukan yang berasal dari minyak nabati. Diesel jenis ini memiliki beberapa keunggulan jika dibandingkan dengan diesel yang memiliki bahan baku dari fosil karena ramah lingkungan dan tidak menimbulkan akumulasi karbon dioksida (CO₂) di atmosfer. Saat ini terdapat beberapa proses yang dapat digunakan untuk menghasilkan green diesel seperti: hydroprocess trigliserida dan pirolisis bahan lignoselulosa yang berasal dari bahan yang mengandung karbohidrat. Pada setiap proses dibahas kondisi operasi untuk hasil produksi maksimum. Selain itu penggunaan katalis yang sesuai juga mempengaruhi hasil produksi. Artikel ini bertujuan untuk membahas tentang green diesel serta teknik produksi yang digunakan. Berdasarkan studi literatur yang dilakukan, didapatkan bahwa tidak semua teknologi produksi menggunakan bahan serta katalis yang sama. Perlu adanya pertimbangan pemilihan teknologi produksi sesuai dengan tujuan dan penerapannya.
References
L. Parinduri dan T. Parinduri, “Konversi Biomassa Sebagai Sumber Energi Terbarukan,” JET (Journal Electr. Technol), vol. 5, no. 2, hal. 88–92, 2020.
A. S. Pramudiyanto dan S. W. A. Suedy, “Energi Bersih dan Ramah Lingkungan dari Biomassa untuk Mengurangi Efek Gas Rumah Kaca dan Perubahan Iklim yang Ekstrim,” J. Energi Baru dan Terbarukan, vol. 1, no. 3, hal. 92–105, 2020.
H. Hadrah, M. Kasman, dan F. M. Sari, “Analisis Minyak Jelantah Sebagai Bahan Bakar Biodiesel dengan Proses Transesterifikasi,” J. Daur Lingkung, vol. 1, no. 1, hal. 16, 2018.
Monisha J , Harish A , Sushma R , Krishna Murthy T P, Blessy B Mathew, “Biodiesel : A Review," Int. Journal of Engineering Research and Applications, vol. 3, no. 1, hal. 902– 912, 2014.
N. Suleman, Abas, dan M. Paputungan, “Esterifikasi dan Transesterifikasi Stearin Sawit untuk Pembuatan Biodiesel,” J. Tek, vol. 17, no. 1, hal. 66–77, 2019.
A. E. Ghaly, D. Dave, M. S. Brooks, and S. Budge, “Production of biodiesel by enzymatic transesterification: Review,” Am. J. Biochem. Biotechnol, vol. 6, no. 2, hal. 54–76, 2010.
Y. Kussuryani and A. R. S. Ali, “Teknologi Produksi Green Diesel untuk Pembuatan Bahan Bakar Minyak Alternatif,” Lembaran Publ. Miny. dan gas bumi, vol. 44, no. 1, hal. 32– 38, 2022.
T. N. Kalnes et al., “Green diesel production by hydrorefining renewable feedstocks,” Greenea, vol. 2, no. 4, hal. 1–3, 2015.
A. Afshar Taromi and S. Kaliaguine, “Green diesel production via continuous hydrotreatment of triglycerides over mesostructured Γ-alumina supported NiMo/CoMo catalysts,” Fuel Process. Techno, vol. 171, no. 1, hal. 20–30, 2018.
G. Di Vito Nolfi, K. Gallucci, and L. Rossi, “Green diesel production by catalytic hydrodeoxygenation of vegetables oils,” Int. J. Environ. Res. Public Health, vol. 18, no. 24, 2021.
E. Kordouli, L. Sygellou, C. Kordulis, K. Bourikas, and A. Lycourghiotis, “Probing the synergistic ratio of the NiMo/Γ-Al2O3 reduced catalysts for the transformation of natural triglycerides into green diesel,” Appl. Catal. B Environ, vol. 209, hal. 12–22, 2017.
P. A. Cremonez, J. G. Teleken, and T. Weiser Meier, “Potential of Green Diesel to Complement the Brazilian Energy Production: A Review,” Energy and Fuels, vol. 35, no. 1, hal. 176–186, 2021.
A. L. Marshall and P. J. Alaimo, “Useful products from complex starting materials: Common chemicals from biomass feedstocks,” Chem. - A Eur. J, vol. 16, no. 17, hal. 4970–4980, 2010.
N. Arpi, “Profil Medium Chain Fatty Acids (MCFA) Dan Sifat Kimia Minyak Kelapa (Virgin Coconut Oil / VCO, Minyak Simplah , Pliek U, Klentik , dan Kopra ) Dibandingkan dengan Minyak Sawit,” Sagu, vol. 12, no. 2, hal. 23–31, 2013.
T. M. Mata, A. A. Martins, and N. S. Caetano, “Microalgae for biodiesel production and other applications: A review,” Renew. Sustain. Energy Rev, vol. 14, no. 1, hal. 217–232, 2010.
M. R. Hidayat, “Teknologi Pretreatment Bahan Lignoselulosa,” Biopropal Ind, vol. 4, no. 1, hal. 33–48, 2013.
P. Harmsen, W. Huijgen, L. López, and R. Bakker, “Literature Review of Physical and Chemical Pretreatment Processes for Lignocellulosic Biomass,” Food Biobased Res., no. January, hal.1–49, 2010,
A. Matsutani, T. Harada, S. Ozaki, and T. Takaoka, "Inhibitory effects of combination of CDDP and cepharanthin on the cultured cells from rat ascites hepatoma," Science and Technology Information Site for Articles, Patents, Research Information, vol. 28, no. 3. 1993.
A. K. Kumar and S. Sharma, “Recent updates on different methods of pretreatment of lignocellulosic feedstocks: a review,” Bioresour. Bioprocess, vol. 4, no. 1, 2017.
R. Sotelo-Boyas, F. Trejo-Zarraga, and F. de Jesus Hernandez-Loyo, “Hydroconversion of Triglycerides into Green Liquid Fuels,” Intech Open Science, vol. 10, hal. 1-30, 2012.
K. E. Leon, A. M. Fruin, S. L. Nowotarski, and J. R. DiAngelo, “The regulation of triglyceride storage by ornithine decarboxylase (Odc1) in Drosophila,” Biochem. Biophys.Res.Commun, vol. 523, no. 2, hal. 429–433, 2020.
S. K. Kim, S. Brand, H. S. Lee, Y. Kim, and J. Kim, “Production of renewable diesel by hydrotreatment of soybean oil: Effect of reaction parameters,” Chem. Eng. J, vol. 228, hal. 114–123, 2013.
M. Stumborg, A. Wong, and E. Hogan, “Hydroprocessed vegetable oils for diesel fuel improvement,” Bioresour. Technol, vol. 56, no. 1, hal. 13–18, 1996.
T.M. Sankaranarayanan, M. Banu, A. Pandurangan, and S. Sivasanker, “Hydroprocessing of sunflower oil-gas oil blends over sulfided Ni-Mo-Al-zeolite beta composites,” Bioresour. Technol, vol. 102, no. 22, hal. 10717–10723, 2011.
D. Kochetkova, J. Blažek, P. Šimáček, M. Staš, and Z. Beňo, “Influence of rapeseed oil hydrotreating on hydrogenation activity of CoMo catalyst,” Fuel Process. Technol, vol. 142, hal. 319–325, 2016.
A. Srifa, K. Faungnawakij, V. Itthibenchapong, and S. Assabumrungrat, “Roles of monometallic catalysts in hydrodeoxygenation of palm oil to green diesel,” Chem. Eng. J, vol. 278, hal. 249–258, 2015.
D. Kubička, J. Horáček, M. Setnička, R. Bulánek, A. Zukal, and I. Kubičková, “Effect of support-active phase interactions on the catalyst activity and selectivity in deoxygenation of triglycerides,” Appl. Catal. B Environ, vol. 145, hal. 101–107, 2014.
I. Rusnadi, J. M. Amin, A. Zikri, R. Sabatini, and P. N. Sriwijaya, “Penggunaan Katalis NiMo / Al2O3 Pada Proses Hydrotreating Minyak Jelantah Menjadi Green Diesel Jurusan Teknik Kimia program Studi Sarjana Terapan Teknik Energi , The Use Of NiMo / Al2O3 Catalysts In The Hydrotreating Process Cooking Oil Into G,” Jurnal Pendidikan dan Teknologi Indonesia, vol. 1, no. 12, hal. 465–474, 2021.
C. Kordulis, K. Bourikas, M. Gousi, E. Kordouli, and A. Lycourghiotis, “Development of nickel based catalysts for the transformation of natural triglycerides and related compounds into green diesel: A critical review,” Appl. Catal. B Environ, vol. 181, hal. 156–196, 2016.
K. Murata, Y. Liu, M. Inaba, and I. Takahara, “Production of synthetic diesel by hydrotreatment of jatropha oils using Pt-Re/H-ZSM-5 catalyst,” Energy and Fuels, vol. 24, no. 4, hal. 2404–2409, 2010.
F. Luis and G. Moncayo, “Konversi Termal Kayu Ketapang (Terminalia Catappa L.) Menjadi Bio-Oil Dengan Teknologi Pirolisis Menggunakan Katalis Nimo/NZA,” Jurnal Online Mahasiswa Fakultas Teknik, vol. 2, no. 1 hal. 1-8, 2015.
J. Sarkar and S. Bhattacharyya, “Application of graphene and graphene-based materials in clean energy-related devices Minghui,” Arch. Thermodyn, vol. 33, no. 4, hal. 23–40, 2012.
D. Meier and O. Faix, “State of the art of applied fast pyrolysis of lignocellulosic materials - A review,” Bioresour. Technol, vol. 68, no. 1, hal. 71–77, 1999.
S. Czernik and A. V. Bridgwater, “Overview of applications of biomass fast pyrolysis oil,” Energy and Fuels, vol. 18, no. 2, hal. 590–598, 2004.
J. Wildschut, F. H. Mahfud, R. H. Venderbosch, and H. J. Heeres, “Hydrotreatment of
Fast Pyrolysis Oil Using Heterogeneous Noble-Metal Catalysts” Ind. Eng. Chem, vol. 48, hal. 10324–10334, 2009.
D. C. Elliott, “Transportation fuels from biomass via fast pyrolysis and hydroprocessing,” Wiley Interdiscip. Rev. Energy Environ, vol. 2, no. 5, hal. 525–533, 2013.
H. Wang, D. C. Elliott, R. J. French, S. Deutch, and K. Iisa, “Biomass conversion to produce hydrocarbon liquid fuel via hot-vapor filtered fast pyrolysis and catalytic hydrotreating,” J. Vis. Exp, vol. 2016, no. 118, hal. 1–13, 2016.
A. V. Bridgwater, “Review of fast pyrolysis of biomass and product upgrading,” Biomass and Bioenergy, vol. 38, hal. 68–94, 2012.
S. S. Ail and S. Dasappa, “Biomass to liquid transportation fuel via Fischer Tropsch synthesis - Technology review and current scenario,” Renew. Sustain. Energy Rev, vol. 58, hal. 267–286, 2016.
A. De Klerk, F. R. Catalysis, S. Africa, S. Africa, and E. Section, “Thermal Cracking of Fischer - Tropsch Waxes,” Ind. Eng. Chem, vol. 46, hal. 5516–5521, 2007.
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