Pengaruh Gelombang Ultrasonik pada Pembuatan Sabun Transparan dari Minyak Kelapa (Cocos nucifera) dan Minyak Ayam (Gallus domesticus)

Authors

  • Aman Santoso Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Negeri Malang, Jl. Semarang No. 5 Malang 65145, Indonesia
  • Rohman Fantusi Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Negeri Malang, Jl. Semarang No. 5 Malang 65145, Indonesia
  • Siti Marfu’ah Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Negeri Malang, Jl. Semarang No. 5 Malang 65145, Indonesia
  • Sumari Sumari Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Negeri Malang, Jl. Semarang No. 5 Malang 65145, Indonesia

DOI:

https://doi.org/10.33795/jtkl.v5i1.175

Keywords:

chicken oil, coconut oil, saponification, transparent soap, ultrasonic waves

Abstract

Transparent soap is synthesized from vegetable oils with alkaline bases through the saponification reaction with the addition of a transparent agent. The different material characteristics of coconut oil (Cocos nucifera) and chicken oil (Gallus domesticus) have the potential to produce unique transparent soap. Ultrasonic wave cavitation homogenizes the mixture and accelerates the reaction rate. The purpose of this research is to synthesize transparent soap from coconut oil and chicken oil and compared the soap produced using ultrasonic waves and with soap from the heating method. This experimental laboratory research was carried out with the stages of preparation and characterization of coconut oil and chicken oil, followed by saponification of coconut oil and chicken oil accompanied by ultrasonic waves. Characterization of the synthesized transparent soap. The results in this study indicate that soaps made from coconut oil are more transparent than those made from chicken oil, and soaps made with ultrasonic waves are more transparent than those made by normal heating. The ultrasonic transparent soap character of coconut oil has a moisture content of 22.02%, the non-saponified fraction 1.01%, insoluble part of alcohol by 1.79%, free alkaline by 0.04%, pH 9.35, and this is in accordance with SNI for soap except for its water content. Meanwhile, ultrasonic soap from chicken oil has a moisture content of 23.26%, non-saponified fraction 5.57%, the insoluble portion of alcohol was 4.69%, free alkaline 0.12%, pH 9.60, this is not in accordance with SNI soap. The soap produced by the ultrasonic method with coconut oil has the best character and has the most compatibility with SNI for solid soap.

References

C. Muslim, V. Darwis, Peningkatan Kesejahteraan Petani melalui Inovasi Teknologi Produk Turunan Kelapa dalam di Sulawesi Barat, Jurnal Sosial Ekonomi Pertanian dan Agribisnis, vol. 14, no. 1, hal. 18–27, 2017.

I. A. K. Pramushinta, P. S. Ajiningrum, Formulasi Sediaan Sabun Padat Transparan dengan Penambahan Ekstrak Biji Bunga Matahari (Helianthus annus L.), STIGMA: Jurnal Matematika dan Ilmu Pengetahuan Alam Unipa, vol. 11, no. 1, hal. 77–84, 2018.

Febriyenti, L. I. Sari, R. Nofita, Formulasi Sabun Transparan Minyak Ylang-Ylang dan Uji Efektivitasterhadap Bakteri Penyebab Jerawat, Jurnal Sains Farmasi & Klinis, vol. 1, no. 1, hal. 61–71, 2014.

J. W. Hill, C. S. Hill, Transparent Soap, J. Chem. Educ., vol. 57, no. 5, hal. 372, 1980.

T. Moaddel, M. I. Hill, Transparent and Translucent Soaps, in Soap Manufacturing Technology 2nd Edition, Accademic Press and AOCS Press, 2016.

E. D. George, D. J. Raymond, Formulation of Traditional Soap Cleansing Systems, in Soap Manufacturing Technology 2nd Edition, Accademic Press and AOCS Press, 2016.

N. P. Vidal, O. A. Adigun,T. H. Pham, A. Mumtaz, C. Manful, G. Callahan, P. Stewart, D. Keough, R. H. Thomas, The Effects of Cold Saponification on the Unsaponified Fatty Acid Composition and Sensory Perception of Commercial Natural Herbal Soaps, Mol. J. Synth. Chem. Nat. Prod. Chem., vol. 23, no. 9, hal. 1–20, 2018.

A. Widyasanti, C. L. Farddani, D. Rohdiana, Pembuatan Sabun Padat Transparan Menggunakan Minyak Kelapa Sawit (Palm Oil) Dengan Penambahan Bahan Aktif Ekstrak Teh Putih (Camellia Sinensis), Jurnal Tenik Pertanian Lampung, vol. 5, no. 3, hal. 125–136, 2016.

S. I. S. Dai, M. A. Asnawi, Analisis Pengembangan Produk Turunan Kelapa Di Provinsi Gorontalo, Front. J. Sains Dan Teknol., vol. 1, no. 1, hal. 17–26, 2018.

J. Salimon, B. M. Abdullah, N. Salih, Saponification of Jatropha curcas Seed Oil: Optimization by D-Optimal Design, Int. J. Chem. Eng., vol. 2012, ID 574780, hal. 1–6, 2012.

N. Pasaribu, Minyak Buah Kelapa Sawit. Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Sumatera Utara, Indonesia, 2004.

A. Widyasanti, A. H. Hasna, The study of transparent soap making from virgin coconut oil-based with the addition of white tea extract as an active ingredients, J. Penelit. Teh dan Kina, vol. 19, no. 2, hal. 179–195, 2016.

T. Setiawati, U. Atmomarsono, B. Dwiloka, Kadar Lemak dan Profil Asam Lemak Jenuh, Asam Lemak Tak Jenuh Daging Ayam Broiler dengan Pemberian Pakan Mengandung Tepung Daun Kayambang (Salvinia molesta), Jurnal Teknologi Hasil Pertanian, vol. 9, no. 2, hal. 1–7, 2016.

R. V Pratama, M. Mardiana, H. Niawanti, Pemanfaatan Limbah Lemak Ayam Broiler (Gallus domesticus) Sebagai Bahan Baku Pembuatan Biodiesel Melalui Proses Transesterifikasi, J. Chemurgy, vol. 2, no. 2, hal. 6–14, 2018.

I. Aziz, Pemanfaatan Limbah Kulit Ayam Broiler sebagai Bahan Baku Pembuatan Biodiesel, J. Kim. Valensi, vol. 4, no. 2, hal. 90–97, 2014.

S. N. Hayati, V. T. Rosyida, C. Darsih, K. Nisa, A. W. Indrianingsih, W. Apriyana, D. Ratih, Physicochemical properties, antimicrobial and antioxidant activity of ganoderma transparent soap, IOP Conf. Ser. Earth Environ. Sci., vol. 462, 12047, 2020.

R. Cella, H. A. Stefani, Ultrasonic Reactions, in Green Techniques for Organic Synthesis and Medicinal Chemistry, 2nd ed, W. Zhang dan B. W. Cue, Eds. John Wiley & Sons, Ltd, 2018, hal 343–371.

A. Santoso, Sumari, A. Salim, S. Marfu’ah, Synthesis of Methyl Ester from Chicken Oil and Methanol Using Heterogeneous Catalyst of CaO-MgO as well as Characterization Its Potential as a Biodiesel Fuel, J. Phys.: Conf. Ser., vol. 1093, p. 12035, 2018.

G. Möller, K. M. Kalumuck, G. L. Chahine, Homogeneous and Heterogeneous Processes in Ultrasonic and Hydrodynamic Cavitation: Application to Treatment of Aqueous Biocides, Pesticides and Herbicides. Jun. 24, 2016.

L. F. Chuah, Influence of green catalyst on transesterification process using ultrasonic-assisted, J. Clean. Prod, vol. 136, hal. 14–22, 2016.

BSN, Sabun Mandi SNI 06-3532-1994. Jakarta: Badan Standardisasi Nasional, 1994.

Munn & Company, Transparent Soap, Sci. Am., vol. 8, no. 51, 1853.

N. F. Zebua, S. Sudewi, M. Prihatini, Formulation and Evaluation of Transparent Soap from Bone Cow Collagen (Bos sp.) as Moisturizer, J. Pharm. Sci., vol. 2, no. 1, hal. 1–9, 2019.

Hernani, T. K. Bunasor, Fitriati, Formula Sabun Transparan Antijamur dengan Bahan Aktif Ekstrak Lengkuas (Alpinia galanga L. Swartz.), Buletin Penelitian Tanaman Rempah dan Obat, vol. 21, no. 2, hal. 192–205, 2010.

S. B. Shrivastava, Soap, Detergent and Parfume Industry. New Delhi: Small Industry Research Institute, 1982.

Downloads

Published

2021-04-29

Issue

Section

Articles