Pengaruh Waktu Terhadap Temperatur Aktivasi dari Kulit Pisang (Musa paradisiaca L.) dalam Pembuatan Katalis

Authors

  • Yuni Kurniati Departemen Teknik Kimia, Unversitas Internasional Semen Indonesia (UISI), Kompleks PT. Semen Indonesia (Persero) Tbk., Jl. Veteran, Gresik, 61122
  • Eka Lutfi Septiani Departemen Teknik Kimia, Unversitas Internasional Semen Indonesia (UISI), Kompleks PT. Semen Indonesia (Persero) Tbk., Jl. Veteran, Gresik, 61122
  • Okky Putri Prastuti Departemen Teknik Kimia, Unversitas Internasional Semen Indonesia (UISI), Kompleks PT. Semen Indonesia (Persero) Tbk., Jl. Veteran, Gresik, 61122
  • Victor Purnomo Departemen Teknik Kimia, Unversitas Internasional Semen Indonesia (UISI), Kompleks PT. Semen Indonesia (Persero) Tbk., Jl. Veteran, Gresik, 61122
  • Sri Sugmah Nur Dewi Departemen Teknik Kimia, Unversitas Internasional Semen Indonesia (UISI), Kompleks PT. Semen Indonesia (Persero) Tbk., Jl. Veteran, Gresik, 61122
  • Imam Mahmuddin Departemen Teknik Kimia, Unversitas Internasional Semen Indonesia (UISI), Kompleks PT. Semen Indonesia (Persero) Tbk., Jl. Veteran, Gresik, 61122

DOI:

https://doi.org/10.33795/jtkl.v4i1.134

Keywords:

Activation, catalyst, banana peel, sulfonation.

Abstract

Banana peels include agricultural waste that contains lignocellulosic components (holocellulose and lignin) and carbohydrate content which is quite high. Banana peel is quite potential to be used as a substrate in producing catalysts. Acid catalyst is one type of catalyst that plays an important role in chemical processes. Chemical activation is the process of breaking the carbon chains of organic compounds by using chemicals. In this way, the activation process is carried out using chemicals (activators) as activating agents. This study aims to study the effect of activation temperature temrhadao from the optimum mass ratio of carbon-KOH in the synthesis process of banana skin charcoal based catalysts so as to produce a catalyst with the most optimal characteristics, and calcination temperature as a physical chemical process in the synthesis of banana skin charcoal based catalysts. The method of making the catalyst is done by calcination to decompose the carbon source into carbon so that the composite is formed according to the temperature that has been varied. After forming carbon-KOH composite, then sulfonation is carried out using concentrated sulfuric acid according to the specified temperature. Activation with KOH at activation temperatures of 300°C, 350°C and 400°C. In this research, the activation process can run optimally at temperatures of 300 °C, 350 °C, and 400 °C which are characterized by the presence of white smoke that has not come out anymore because carbon has reacted with KOH.

References

B. Basse, Compost Engineering, London : An Arbour Science, 2000.

A. Yosephine, Pemanfaatan ampas tabu dan kulit pisang dalam pembuatan kertas serat campuran. Jurnal Teknik Kimia Indonesia, vol. 11, no. 2, hal. 94-100, 2012.

D. Darmono, Lingkungan Hidup dan Pencemaran (Hubungannya dengan Toksikologi Senyawa Logam), Jakarta: UI Press, 2001.

L. Foist, The Ostwald Process & Catalytic Oxidation of Ammonia, Study.com, 2019.

A. Dabrowski, P. Podkoscielny, Z. Hubicki, M. Barczak, Adsorption of phenolic compounds by activated carbon, Chemosphere, vol. 58, hal. 1049-1070, 2005.

S. Sani, Pembuatan karbon aktif dari tanah gambut, Jurnal Teknik Kimia, vol. 5, no.2, hal. 400-406, 2011.

E. Nuramanah, H. Sholihin, W. Siswaningsih, Kajian Aktivitas Antioksidan Kulit Pisang Raja Bulu (Musa paradisiaca L. Var Sapientum) dan Produk Olahannya, J. Si. Tek. Kim., vo. 4, no. 1, hal. 1-7, 2013.

E. Hewett, Stem A and Mrs. Wildfong. Banana Peel Heavy Metal Water Filter. http://users.wpi.edu, diakses 30 Januari 2017, 2011.

M. Sudibandriyo, PhD. dissertation: A Generalized Ono-Kondo Lattice Model for High Pressure on Carbon Adsorben, Oklahama State Univ., Oklahoma, USA, 2003.

N. Nurfitria, K. Febriyantiningrum, W. P. Utomo, Z. V. Nugraheni, D. D. Pangastuti, H. Maulida, F. N. Ariyanti, Pengaruh Konsentrasi Aktivator Kalium Hidroksida (KOH) pada Karbon Aktif dan Waktu Kontak Terhadap Daya Adsorpsi Logam Pb dalam Sampel Air Kawasan Mangrove Wonorejo Surabaya, Akta Kimia Indonesia, vol. 4, no. 1, hal. 75-85, 2019.

Downloads

Published

2020-04-28

Issue

Section

Articles