ANALISA PERFORMA BIOMEMBRAN FILTRASI LIMBAH CAIR BATIK BERBASIS BACTERIAL CELLULOSE LIMBAH KULIT NANAS TERIMPREGNASI PVA
DOI:
https://doi.org/10.33795/distilat.v12i1.7210Keywords:
bacterial cellulose, PVA, kulit nanas, filtrasi, limbah cair batikAbstract
Batik merupakan salah satu komoditas tekstil dengan produktivitas tinggi, namun proses produksinya menghasilkan limbah cair yang mengandung bahan kimia berbahaya. Untuk mengatasi permasalahan ini, dikembangkan biomembran filtrasi berbasis bacterial cellulose dari limbah kulit nanas menggunakan Acetobacter xylinum. Biomembran ini diperkuat dengan polivinil alkohol (PVA) untuk meningkatkan sifat fisik dan mekanisnya. Penelitian ini bertujuan untuk memproduksi serta menganalisis performa biomembran pada filtrasi limbah cair batik. Tahapan penelitian terdiri dari tiga tahap: (1) fabrikasi bacterial cellulose dari limbah kulit nanas, (2) impregnasi PVA dengan variasi konsentrasi (1; 1,5; 2; dan 2,5% m/v dalam 100 mL akuades), dan (3) karakterisasi performa membran. Hasil menunjukkan bahwa peningkatan konsentrasi PVA menurunkan porositas dan fluks membran, mengindikasikan perubahan sifat permeabilitasnya. Analisis FTIR mengonfirmasi keberadaan selulosa melalui pergeseran bilangan gelombang pada gugus -OH, C-H, dan C-O-C akibat impregnasi PVA. Dengan demikian, biomembran berbasis limbah kulit nanas dengan impregnasi PVA memiliki potensi sebagai media filtrasi limbah cair dalam industri batik.
References
A. Fatima, P. Ortiz-Albo, L. A. Neves, F. X. Nascimento, and J. G. Crespo, “Biosynthesis and characterization of bacterial cellulose membranes presenting relevant characteristics for air/gas filtration,” J Memb Sci, vol. 674, May 2023, doi: 10.1016/j.memsci.2023.121509.
F. Galiano, K. Briceño, T. Marino, A. Molino, K. V. Christensen, and A. Figoli, “Advances in biopolymer-based membrane preparation and applications,” J Memb Sci, vol. 564, pp. 562–586, 2018, doi: https://doi.org/10.1016/j.memsci.2018.07.059.
D. Reis, A. Pereira, G. Scheidt, and D. Pereira, “Plant and Bacterial Cellulose: Production, Chemical Structure, Derivatives and Applications,” Orbital: The Electronic Journal of Chemistry, vol. 11, Mar. 2019, doi: 10.17807/orbital.v11i5.1349.
A. J. Brown, “XLIII.—On an acetic ferment which forms cellulose,” Journal of The Chemical Society, Transactions, vol. 49, pp. 432–439, [Online]. Available: https://api.semanticscholar.org/CorpusID:93665151
R. Naomi, R. B. H. Idrus, and M. B. Fauzi, “Plant-vs. Bacterial-derived cellulose for wound healing: A review,” Sep. 01, 2020, MDPI AG. doi: 10.3390/ijerph17186803.
J. Wang, J. Tavakoli, and Y. Tang, “Bacterial cellulose production, properties and applications with different culture methods – A review,” Carbohydr Polym, vol. 219, pp. 63–76, 2019, doi: https://doi.org/10.1016/j.carbpol.2019.05.008.
Y. Hu, M. Yue, F. Yuan, L. Yang, C. Chen, and D. Sun, “Bio-inspired fabrication of highly permeable and anti-fouling ultrafiltration membranes based on bacterial cellulose for efficient removal of soluble dyes and insoluble oils,” J Memb Sci, vol. 621, p. 118982, 2021, doi: https://doi.org/10.1016/j.memsci.2020.118982.
C. J. S. Galdino et al., “Use of a bacterial cellulose filter for the removal of oil from wastewater,” Process Biochemistry, vol. 91, pp. 288–296, 2020, doi: https://doi.org/10.1016/j.procbio.2019.12.020.
A. Fatima, P. Ortiz-Albo, L. A. Neves, F. X. Nascimento, and J. G. Crespo, “Biosynthesis and characterization of bacterial cellulose membranes presenting relevant characteristics for air/gas filtration,” J Memb Sci, vol. 674, May 2023, doi: 10.1016/j.memsci.2023.121509.
A. Figoli et al., “Towards Non‐toxic Solvents for Membrane Preparation: A Review,” ChemInform, vol. 45, 2014, [Online]. Available: https://api.semanticscholar.org/CorpusID:197239550
T. Owoeye, A. Kehinde, O. O. Ajayi, A. Afolalu, J. Popoola, and O. Ajani, “Phytochemical constituents and proximate analysis of dry pineapple peels,” IOP Conf Ser Earth Environ Sci, vol. 993, p. 12027, Mar. 2022, doi: 10.1088/1755-1315/993/1/012027.
X. Hu, M. Zhao, G. Song, and H. Huang, “Modification of pineapple peel fibre with succinic anhydride for Cu 2+, Cd2+ and Pb2+ removal from aqueous solutions,” Environ Technol, vol. 32, no. 7, pp. 739–746, 2011, doi: 10.1080/09593330.2010.510853.
L. Meena, A. S. Sengar, R. Neog, and C. K. Sunil, “Pineapple processing waste (PPW): bioactive compounds, their extraction, and utilisation: a review,” J Food Sci Technol, vol. 59, no. 11, pp. 4152–4164, 2022, doi: 10.1007/s13197-021-05271-6.
A. Urbaninggar and S. Fatimah, “Pengaruh Penambahan Ekstrak Kulit Nanas dan Gula pada Karakteristik Nata De Soya dari Limbah Cair Tahu,” Indonesian Journal of Chemical Analysis, vol. 4, no. 2, pp. 82–91, 2021, doi: 10.20885/ijca.vol4.iss2.art5.
N. Fuadi, P. Sulaiman, A. Purwadana, B. Wahyudi, and N. H. Fithriyah, “Studi Literatur Pemanfaatan Selulosa Asetat Limbah Kulit Nanas Sebagai Bahan Baku Pembuatan Membran Untuk Desalinasi,” 2022.
V. Vatanpour, O. O. Teber, M. Mehrabi, and I. Koyuncu, “Polyvinyl alcohol-based separation membranes: a comprehensive review on fabrication techniques, applications and future prospective,” Mater Today Chem, vol. 28, p. 101381, 2023, doi: https://doi.org/10.1016/j.mtchem.2023.101381.
H. R. Fidiastuti and A. S. Lathifah, “Uji Karakteristik Limbah Cair Industri Batik Tulungagung: Penelitian Pendahuluan,” 2018.
R. Al-Tohamy et al., “A critical review on the treatment of dye-containing wastewater: Ecotoxicological and health concerns of textile dyes and possible remediation approaches for environmental safety,” Ecotoxicol Environ Saf, vol. 231, p. 113160, 2022, doi: https://doi.org/10.1016/j.ecoenv.2021.113160.
X. Gong, Y. Wang, H. Zeng, M. Betti, and L. Chen, “Highly porous, hydrophobic, and compressible cellulose nanocrystals/PVA aerogels as recyclable absorbents for oil-water separation,” ACS Sustain Chem Eng, vol. 7, May 2019, doi: 10.1021/acssuschemeng.9b00066.
K. Qiu and A. N. Netravali, “Bacterial cellulose-based membrane-like biodegradable composites using cross-linked and noncross-linked polyvinyl alcohol,” J Mater Sci, vol. 47, no. 16, pp. 6066–6075, Aug. 2012, doi: 10.1007/s10853-012-6517-9.
U. Fathanah et al., “Modifikasi Membran Polyethersulfone dengan Penambahan Nanopartikel Mg(OH)2 dalam Pelarut Dimethyl Sulfoxide,” ALCHEMY Jurnal Penelitian Kimia, vol. 18, no. 2, p. 165, Sep. 2022, doi: 10.20961/alchemy.18.2.58248.165-173.
S. R. Panda, M. Mukherjee, and S. De, “Preparation, characterization and humic acid removal capacity of chitosan coated iron-oxide- polyacrylonitrile mixed matrix membrane,” Journal of Water Process Engineering, vol. 6, pp. 93–104, 2015, doi: https://doi.org/10.1016/j.jwpe.2015.03.007.
D. Amiyati, D. Indarti, and Y. Muflihah, “Pengaruh Variasi Waktu Penguapan Terhadap Kinerja Membran Selulosa Asetat pada Proses Ultrafiltrasi,” BERKALA SAINSTEK, vol. 5, p. 7, Mar. 2017, doi: 10.19184/bst.v5i1.5368.
F. Zulfi, “Karakteristik Fluks Membran dalam Proses Filtrasi Limbah Cair Industri Pelapisan Logam,” Jurnal Biofisika, vol. 10, no. 1, 2014.
T. N. Ikhsan, K. Khabibi, and R. A. Lusiana, “Sintesis Membran Kitosan Tertaut Silang Tripolifosfat dengan Paduan Polivinil Alkohol untuk Permeasi Kreatinin,” Greensphere: Journal of Environmental Chemistry, 2024, [Online]. Available: https://api.semanticscholar.org/CorpusID:272261481
A. Rusmaningsih, I. Syahbanu, and L. Destiarti, “Uji Fluks Membran Polisulfon/Polietilen Glikol/Selulosa Asetat Dari Nata De Coco,” vol. 7, no. 3, pp. 84–90, 2018.
O. Sulaeman, “Desain Pengolahan Air Menggunakan Membran Ultrafiltrasi Kapasitas 50m3/Hari,” Jurnal Rekayasa Lingkungan, vol. 11, Mar. 2018, doi: 10.29122/jrl.v11i1.3025.
M. Khasanah, B. Yusuf, and Am. S. Panggabean, “Membran Selulosa Asetat Dari Mahkota Buah Nanas (Ananas Comocus) Sebagai Filter Dalam Tahapan Pengolahan Air Limbah Sarung Tenun Samarinda,” in Prosiding Seminar Nasional Kimia 2017, 2017, p. 23.
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